Trace water mediated growth of oriented single-crystalline mesoporous metal-organic frameworks on gold nanorods.

Here we report, for the first time, the growth of single-crystalline mesoporous MOFs with well-controlled orientation on the surface of gold nanorods. Importantly, it showed that trace amounts of water could induce the formation of MOFs of different phases and shapes, which was critical for the synthesis of such mesoporous heterostructures.

[1]  Z. Tang,et al.  Coordination-responsive drug release inside gold nanorod@metal-organic framework core–shell nanostructures for near-infrared-induced synergistic chemo-photothermal therapy , 2018, Nano Research.

[2]  L. Gu,et al.  Zirconium-Porphyrin-Based Metal-Organic Framework Hollow Nanotubes for Immobilization of Noble-Metal Single Atoms. , 2018, Angewandte Chemie.

[3]  Chunhua Yan,et al.  Heterodimers Made of Upconversion Nanoparticles and Metal-Organic Frameworks. , 2017, Journal of the American Chemical Society.

[4]  Anita J. Hill,et al.  Centimetre-scale micropore alignment in oriented polycrystalline metal-organic framework films via heteroepitaxial growth. , 2017, Nature materials.

[5]  Christopher A. Trickett,et al.  Plasmon-Enhanced Photocatalytic CO(2) Conversion within Metal-Organic Frameworks under Visible Light. , 2017, Journal of the American Chemical Society.

[6]  B. Grzybowski,et al.  Large-Area, Freestanding MOF Films of Planar, Curvilinear, or Micropatterned Topographies. , 2017, Angewandte Chemie.

[7]  G. Somorjai,et al.  Copper Nanocrystals Encapsulated in Zr-based Metal-Organic Frameworks for Highly Selective CO2 Hydrogenation to Methanol. , 2016, Nano letters.

[8]  Hong‐Cai Zhou,et al.  Seed-Mediated Synthesis of Metal-Organic Frameworks. , 2016, Journal of the American Chemical Society.

[9]  Jihye Park,et al.  Size-Controlled Synthesis of Porphyrinic Metal-Organic Framework and Functionalization for Targeted Photodynamic Therapy. , 2016, Journal of the American Chemical Society.

[10]  J. Hupp,et al.  Chemical, thermal and mechanical stabilities of metal–organic frameworks , 2016 .

[11]  J. Hupp,et al.  Selective Photooxidation of a Mustard-Gas Simulant Catalyzed by a Porphyrinic Metal-Organic Framework. , 2015, Angewandte Chemie.

[12]  A. Morris,et al.  Concentration Dependent Dimensionality of Resonance Energy Transfer in a Postsynthetically Doped Morphologically Homologous Analogue of UiO-67 MOF with a Ruthenium(II) Polypyridyl Complex. , 2015, Journal of the American Chemical Society.

[13]  A. Hexemer,et al.  Mesoscopic constructs of ordered and oriented metal-organic frameworks on plasmonic silver nanocrystals. , 2015, Journal of the American Chemical Society.

[14]  Wenbin Lin,et al.  Nanoscale Metal–Organic Framework for Highly Effective Photodynamic Therapy of Resistant Head and Neck Cancer , 2014, Journal of the American Chemical Society.

[15]  Jarad A. Mason,et al.  A five-coordinate heme dioxygen adduct isolated within a metal-organic framework. , 2014, Journal of the American Chemical Society.

[16]  S. Granick,et al.  Voids and yolk-shells from crystals that coat particles. , 2014, Journal of the American Chemical Society.

[17]  L. Chou,et al.  Surfactant-directed atomic to mesoscale alignment: metal nanocrystals encased individually in single-crystalline porous nanostructures. , 2014, Journal of the American Chemical Society.

[18]  H. Zhou,et al.  Metal-organic frameworks (MOFs). , 2014, Chemical Society reviews.

[19]  Dawei Feng,et al.  Construction of ultrastable porphyrin Zr metal-organic frameworks through linker elimination. , 2013, Journal of the American Chemical Society.

[20]  G. Wiederrecht,et al.  Layer-by-layer fabrication of oriented porous thin films based on porphyrin-containing metal-organic frameworks. , 2013, Journal of the American Chemical Society.

[21]  Michael O’Keeffe,et al.  The Chemistry and Applications of Metal-Organic Frameworks , 2013, Science.

[22]  S. Kitagawa,et al.  Integration of porous coordination polymers and gold nanorods into core-shell mesoscopic composites toward light-induced molecular release. , 2013, Journal of the American Chemical Society.

[23]  Zhiyong Tang,et al.  Core-shell noble-metal@metal-organic-framework nanoparticles with highly selective sensing property. , 2013, Angewandte Chemie.

[24]  G. Wiederrecht,et al.  Energy transfer from quantum dots to metal-organic frameworks for enhanced light harvesting. , 2013, Journal of the American Chemical Society.

[25]  G. Wiederrecht,et al.  Light-harvesting and ultrafast energy migration in porphyrin-based metal-organic frameworks. , 2013, Journal of the American Chemical Society.

[26]  Zhangwen Wei,et al.  Zirconium-metalloporphyrin PCN-222: mesoporous metal-organic frameworks with ultrahigh stability as biomimetic catalysts. , 2012, Angewandte Chemie.

[27]  Yi Wang,et al.  Imparting functionality to a metal-organic framework material by controlled nanoparticle encapsulation. , 2012, Nature chemistry.

[28]  Jing Wang,et al.  Mesoporous Silica‐Coated Gold Nanorods as a Light‐Mediated Multifunctional Theranostic Platform for Cancer Treatment , 2012, Advanced materials.

[29]  J. Long,et al.  Introduction to metal-organic frameworks. , 2012, Chemical reviews.

[30]  O. Shekhah,et al.  Enantiopure metal-organic framework thin films: oriented SURMOF growth and enantioselective adsorption. , 2012, Angewandte Chemie.

[31]  O. Shekhah,et al.  Intercalation in layered metal-organic frameworks: reversible inclusion of an extended π-system. , 2011, Journal of the American Chemical Society.

[32]  Osami Sakata,et al.  Highly crystalline nanofilm by layering of porphyrin metal-organic framework sheets. , 2011, Journal of the American Chemical Society.

[33]  O. Shekhah,et al.  MOF thin films: existing and future applications. , 2011, Chemical Society reviews.

[34]  Hiroaki Yamanaka,et al.  Surface nano-architecture of a metal-organic framework. , 2010, Nature materials.

[35]  O. Shekhah,et al.  Controlling interpenetration in metal-organic frameworks by liquid-phase epitaxy. , 2009, Nature materials.

[36]  Mostafa A. El-Sayed,et al.  Preparation and Growth Mechanism of Gold Nanorods (NRs) Using Seed-Mediated Growth Method , 2003 .

[37]  Catherine J. Murphy,et al.  Wet Chemical Synthesis of High Aspect Ratio Cylindrical Gold Nanorods , 2001 .

[38]  Jie Tian,et al.  Core–Shell Gold Nanorod@Metal–Organic Framework Nanoprobes for Multimodality Diagnosis of Glioma , 2017, Advanced materials.