A review on self-healing polymers for soft robotics

Abstract The intrinsic compliance of soft robots provides safety, a natural adaptation to its environment, allows to absorb shocks, and protects them against mechanical impacts. However, a literature study shows that the soft polymers used for their construction are susceptible to various types of damage, including fatigue, overloads, interfacial debonding, and cuts, tears and perforations by sharp objects. An economic and ecological solution is to construct future soft robotic systems out of self-healing polymers, incorporating the ability to heal damage. This review paper proposes criteria to evaluate the potential of a self-healing polymer to be used in soft robotic applications. Based on these soft robotics requirements and on defined performance parameters of the materials, linked to the mechanical and healing properties, the different types of self-healing polymers already available in literature are critically assessed and compared. In addition to a description of the state of the art on self-healing soft robotics, the paper discusses the driving forces and limitations to spur the interdisciplinary combination between self-healing polymer science and soft robotics.

[1]  L. Leibler,et al.  Vinylogous Urethane Vitrimers , 2015 .

[2]  Yinghua Jin,et al.  Recent advances in dynamic covalent chemistry. , 2013, Chemical Society reviews.

[3]  Cheng‐Hui Li,et al.  Self‐Healing Polymers Based on Coordination Bonds , 2019, Advanced materials.

[4]  Jeffrey S. Moore,et al.  Self-Healing Polymers and Composites , 2010 .

[5]  J. Ryou,et al.  Review on the self-healing concrete-approach and evaluation techniques , 2019, Journal of Ceramic Processing Research.

[6]  G. Assche,et al.  Selection of healing agents for a vascular self-healing application , 2017 .

[7]  Jiaxi Cui,et al.  Multivalent H-bonds for self-healing hydrogels. , 2012, Chemical communications.

[8]  Howie Choset,et al.  Continuum Robots for Medical Applications: A Survey , 2015, IEEE Transactions on Robotics.

[9]  Krzysztof Matyjaszewski,et al.  Self‐Healing of Covalently Cross‐Linked Polymers by Reshuffling Thiuram Disulfide Moieties in Air under Visible Light , 2012, Advanced materials.

[10]  Paolo Dario,et al.  Biomedical applications of soft robotics , 2018, Nature Reviews Materials.

[11]  N. Sottos,et al.  Autonomic healing of polymer composites , 2001, Nature.

[12]  P. Rohatgi,et al.  Self-Healing Metals and Metal Matrix Composites , 2014 .

[13]  Benjamin C. K. Tee,et al.  An electrically and mechanically self-healing composite with pressure- and flexion-sensitive properties for electronic skin applications. , 2012, Nature nanotechnology.

[14]  Ulrich S. Schubert,et al.  Self-Healing Polymers Based on Reversible Covalent Bonds , 2015 .

[15]  M. Meneghetti,et al.  Advances in self-healing optical materials , 2012 .

[16]  H. Clausen‐Schaumann,et al.  Mechanochemistry: the mechanical activation of covalent bonds. , 2005, Chemical reviews.

[17]  Benjamin K.S. Woods,et al.  Fatigue life testing of swaged pneumatic artificial muscles as actuators for aerospace applications , 2012 .

[18]  Hod Lipson,et al.  Resilient Machines Through Continuous Self-Modeling , 2006, Science.

[19]  Z. Suo,et al.  Fatigue-Resistant elastomers , 2020 .

[20]  Zhongyun Liu,et al.  Breaking the permeability–selectivity trade-off in thin-film composite polyamide membranes with a PEG-b-PSF-b-PEG block copolymer ultrafiltration membrane support through post-annealing treatment , 2019, NPG Asia Materials.

[21]  R. Hoogenboom Hard autonomous self-healing supramolecular materials--a contradiction in terms? , 2012, Angewandte Chemie.

[22]  G. Whitesides,et al.  Soft Actuators and Robots that Are Resistant to Mechanical Damage , 2014 .

[23]  Zhirun Yuan,et al.  Fabrication of Microcapsules by the Combination of Biomass Porous Carbon and Polydopamine for Dual Self-Healing Hydrogels. , 2019, Journal of agricultural and food chemistry.

[24]  Ali Ashrafi,et al.  A review on self-healing coatings based on micro/nanocapsules , 2010 .

[25]  Philipp Michael,et al.  Principles of Self‐Healing Polymers , 2013 .

[26]  Katharina Landfester,et al.  Towards the generation of self-healing materials by means of a reversible photo-induced approach. , 2011, Macromolecular rapid communications.

[27]  F. Jones,et al.  Solid-state healing of resins and composites , 2015 .

[28]  S. Zwaag Self‐Healing Materials , 2007 .

[29]  Xinxing Zhang,et al.  Self-Healing and Reconfigurable Actuators Based on Synergistically Crosslinked Supramolecular Elastomer. , 2020, ACS applied materials & interfaces.

[30]  F. D. Du Prez,et al.  Vitrimers: permanent organic networks with glass-like fluidity , 2015, Chemical science.

[31]  Adrian Bejan,et al.  Vascularized materials: Tree-shaped flow architectures matched canopy to canopy , 2006 .

[32]  Jeffrey S. Moore,et al.  Introduction: self-healing polymers and composites , 2007, Journal of The Royal Society Interface.

[33]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[34]  C. Zhi,et al.  Magnetic-Assisted, Self-Healable, Yarn-Based Supercapacitor. , 2015, ACS nano.

[35]  Luca Gasperini,et al.  The stiffness of living tissues and its implications for tissue engineering , 2020, Nature Reviews Materials.

[36]  Jessica J. Cash,et al.  Room-Temperature Self-Healing Polymers Based on Dynamic-Covalent Boronic Esters , 2015 .

[37]  Nancy R. Sottos,et al.  Self-healing thermoset using encapsulated epoxy-amine healing chemistry , 2012 .

[38]  Bram Vanderborght,et al.  The Safety of a Robot Actuated by Pneumatic Muscles—A Case Study , 2010, Int. J. Soc. Robotics.

[39]  Florian Herbst,et al.  Self-healing polymers via supramolecular forces. , 2013, Macromolecular rapid communications.

[40]  Joost Brancart,et al.  A self-healing polymer network based on reversible covalent bonding , 2013 .

[41]  Ludwik Leibler,et al.  Chemically crosslinked yet reprocessable epoxidized natural rubber via thermo-activated disulfide rearrangements , 2015 .

[42]  C. Buckley,et al.  A Thermoreversible Supramolecular Polyurethane with Excellent Healing Ability at 45 °C , 2015 .

[43]  V. Michaud,et al.  Design of Self-Healing Supramolecular Rubbers with a Tunable Number of Chemical Cross-Links , 2015 .

[44]  Iain A. Anderson,et al.  A self-healing dielectric elastomer actuator , 2014 .

[45]  I. Azcune,et al.  Aromatic disulfide crosslinks in polymer systems: Self-healing, reprocessability, recyclability and more , 2016 .

[46]  C. Keplinger,et al.  A highly stretchable autonomous self-healing elastomer. , 2016, Nature chemistry.

[47]  P. Cochat,et al.  Et al , 2008, Archives de pediatrie : organe officiel de la Societe francaise de pediatrie.

[48]  Ye Shi,et al.  A Conductive Self-Healing Hybrid Gel Enabled by Metal-Ligand Supramolecule and Nanostructured Conductive Polymer. , 2015, Nano letters.

[49]  M. Urban,et al.  Self-healing polymers , 2020, Nature Reviews Materials.

[50]  Daniel A. Kingsley,et al.  Fatigue life and frequency response of braided pneumatic actuators , 2002, Proceedings 2002 IEEE International Conference on Robotics and Automation (Cat. No.02CH37292).

[51]  Daniela Rus,et al.  A Recipe for Soft Fluidic Elastomer Robots , 2015, Soft robotics.

[52]  E. W. Meijer,et al.  Complementary quadruple hydrogen bonding in supramolecular copolymers. , 2005, Journal of the American Chemical Society.

[53]  J. Brancart,et al.  A novel donor-π-acceptor anthracene monomer: Towards faster and milder reversible dimerization , 2019, Tetrahedron.

[54]  Santiago J. Garcia,et al.  Effect of polymer architecture on the intrinsic self-healing character of polymers , 2014 .

[55]  Jie Yin,et al.  Light-reversible hierarchical patterns by dynamic photo-dimerization induced wrinkles , 2017 .

[56]  Atsushi Takahara,et al.  Self-Healing of a Cross-Linked Polymer with Dynamic Covalent Linkages at Mild Temperature and Evaluation at Macroscopic and Molecular Levels , 2015 .

[57]  Yong J. Yuan,et al.  Room-Temperature Self-Healable and Remoldable Cross-linked Polymer Based on the Dynamic Exchange of Disulfide Bonds , 2014 .

[58]  A. Schmidt,et al.  Progress in the remote-controlled activation of self-healing processes , 2016 .

[59]  Jun Xu,et al.  Solvent-free thermo-reversible and self-healable crosslinked polyurethane with dynamic covalent networks based on phenol-carbamate bonds , 2019, Polymer.

[60]  D. Wu,et al.  Self-healing polymeric materials: A review of recent developments , 2008 .

[61]  Jun Zhao,et al.  Self-healing thermoplastic polyurethane (TPU)/polycaprolactone (PCL) /multi-wall carbon nanotubes (MWCNTs) blend as shape-memory composites , 2018, Composites Science and Technology.

[62]  C. R. Becer,et al.  Self-healing and self-mendable polymers , 2010 .

[63]  P. Cordier,et al.  Self-healing and thermoreversible rubber from supramolecular assembly , 2008, Nature.

[64]  Nimali T. Medagedara,et al.  The development of a Gesture Controlled Soft Robot gripping mechanism , 2016, 2016 IEEE International Conference on Information and Automation for Sustainability (ICIAfS).

[65]  Elly M. Tanaka,et al.  Cells keep a memory of their tissue origin during axolotl limb regeneration , 2009, Nature.

[66]  G. Li,et al.  1 – Overview of crack self-healing , 2015 .

[67]  Chuanhui Xu,et al.  Design of Self-Healing Supramolecular Rubbers by Introducing Ionic Cross-Links into Natural Rubber via a Controlled Vulcanization. , 2016, ACS applied materials & interfaces.

[68]  Osman Dogan Yirmibesoglu,et al.  Additive manufacturing of soft robots , 2019, Robotic Systems and Autonomous Platforms.

[69]  James U. Korein,et al.  Robotics , 2018, IBM Syst. J..

[70]  H. Colquhoun Self-repairing polymers: materials that heal themselves. , 2012, Nature chemistry.

[71]  H. Meng,et al.  A review of stimuli-responsive shape memory polymer composites , 2013 .

[72]  Robert J. Wood,et al.  Soft Robotic Grippers for Biological Sampling on Deep Reefs , 2016, Soft robotics.

[73]  M. Urban,et al.  Shape memory effects in self-healing polymers , 2020 .

[74]  Rebecca K. Kramer,et al.  Soft Material Characterization for Robotic Applications , 2015 .

[75]  Bram Vanderborght,et al.  Expressing Emotions with the Social Robot Probo , 2010, Int. J. Soc. Robotics.

[76]  PlanteJean-Sébastien,et al.  Design Principles for Improved Fatigue Life of High-Strain Pneumatic Artificial Muscles , 2016 .

[77]  J. Brancart,et al.  Room-temperature versus heating-mediated healing of a Diels-Alder crosslinked polymer network , 2018, Polymer.

[78]  Jian Ping Gong,et al.  Physical hydrogels composed of polyampholytes demonstrate high toughness and viscoelasticity. , 2013, Nature materials.

[79]  Jianjun Cheng,et al.  Dynamic urea bond for the design of reversible and self-healing polymers , 2014, Nature Communications.

[80]  Guoqiang Li,et al.  Shape memory alloy reinforced vitrimer composite for healing wide-opened cracks , 2020, Smart Materials and Structures.

[81]  Cuicui Su,et al.  Self-Healing Polymeric Materials , 2017 .

[82]  Y. Eom,et al.  Synchronous Curable Deoxidizing Capability of Epoxy-Anhydride Adhesive: Deoxidation Quantification via Spectroscopic Analysis , 2018 .

[83]  S. White,et al.  Self‐Healing Polymer Coatings , 2009 .

[84]  Jean-Sébastien Plante,et al.  Sleeved Bending Actuators for Soft Grippers: A Durable Solution for High Force-to-Weight Applications , 2018, Actuators.

[85]  Pengfei Zhang,et al.  Healing-on-demand composites based on polymer artificial muscle , 2015 .

[86]  Kunhao Yu,et al.  Mechanics of self-healing thermoplastic elastomers , 2020 .

[87]  Nancy R. Sottos,et al.  Triggered Release from Polymer Capsules , 2011 .

[88]  F. Gao,et al.  A high stiffness and self-healable polyurethane based on disulfide bonds and hydrogen bonding , 2020 .

[89]  Yue Zhao,et al.  Light-triggered self-healing and shape-memory polymers. , 2013, Chemical Society reviews.

[90]  M. Podgórski,et al.  Enabling Applications of Covalent Adaptable Networks. , 2019, Annual review of chemical and biomolecular engineering.

[91]  Shinichi Hirai,et al.  A Prestressed Soft Gripper: Design, Modeling, Fabrication, and Tests for Food Handling , 2017, IEEE Robotics and Automation Letters.

[92]  Bram Vanderborght,et al.  Third–Generation Pleated Pneumatic Artificial Muscles for Robotic Applications: Development and Comparison with McKibben Muscle , 2012, Adv. Robotics.

[93]  AmendJohn,et al.  Prosthetic Jamming Terminal Device: A Case Study of Untethered Soft Robotics. , 2016 .

[94]  Guillaume De Bo,et al.  Controlling Reactivity by Geometry in Retro-Diels-Alder Reactions under Tension. , 2017, Journal of the American Chemical Society.

[95]  Darwin Gouwanda,et al.  Moving toward Soft Robotics: A Decade Review of the Design of Hand Exoskeletons , 2018, Biomimetics.

[96]  L. Irusta,et al.  Autonomic healable waterborne organic-inorganic polyurethane hybrids based on aromatic disulfide moieties , 2017 .

[97]  Jiake Wu,et al.  Self-Healing Electronic Materials for a Smart and Sustainable Future. , 2018, ACS applied materials & interfaces.

[98]  Ronald A. Smaldone,et al.  Diels–Alder Reversible Thermoset 3D Printing: Isotropic Thermoset Polymers via Fused Filament Fabrication , 2017 .

[99]  Thomas J. Wallin,et al.  Click chemistry stereolithography for soft robots that self-heal. , 2017, Journal of materials chemistry. B.

[100]  J. Lewis,et al.  Self-healing materials with microvascular networks. , 2007, Nature materials.

[101]  YapHong Kai,et al.  High-Force Soft Printable Pneumatics for Soft Robotic Applications , 2016 .

[102]  Manuel G. Catalano,et al.  A Century of Robotic Hands , 2019, Annu. Rev. Control. Robotics Auton. Syst..

[103]  S. O. Fadlallah,et al.  Bacterial foraging-optimized PID control of a two-wheeled machine with a two-directional handling mechanism , 2017, Robotics and biomimetics.

[104]  Huichan Zhao,et al.  Bio-inspired Design and Additive Manufacturing of Soft Materials, Machines, Robots, and Haptic Interfaces. , 2019, Angewandte Chemie.

[105]  Bram Vanderborght,et al.  Self-healing soft pneumatic robots , 2017, Science Robotics.

[106]  S. Zwaag,et al.  Development of a quasi-static test method to investigate the origin of self-healing in ionomers under ballistic conditions , 2008 .

[107]  R. Sun,et al.  Self-Healing and Shape Memory Linear Polyurethane Based on Disulfide Linkages with Excellent Mechanical Property , 2018, Macromolecular Research.

[108]  A. Georgopoulou,et al.  Piezoresistive Elastomer-Based Composite Strain Sensors and Their Applications , 2020 .

[109]  Wei Chen,et al.  Poly(ionic liquid) hydrogel-based anti-freezing ionic skin for a soft robotic gripper , 2020 .

[110]  Miss A.O. Penney (b) , 1974, The New Yale Book of Quotations.

[111]  Shane K. Mitchell,et al.  Hydraulically amplified self-healing electrostatic actuators with muscle-like performance , 2018, Science.

[112]  Carmel Majidi,et al.  Self-healing materials for soft-matter machines and electronics , 2019, NPG Asia Materials.

[113]  G. Whitesides,et al.  Pneumatic Networks for Soft Robotics that Actuate Rapidly , 2014 .

[114]  D. Floreano,et al.  Soft Robotic Grippers , 2018, Advanced materials.

[115]  Hans-Jörg Schneider,et al.  Binding mechanisms in supramolecular complexes. , 2009, Angewandte Chemie.

[116]  Chuanhui Xu,et al.  Design of self-healable supramolecular hybrid network based on carboxylated styrene butadiene rubber and nano-chitosan. , 2019, Carbohydrate polymers.

[117]  Sung-Youl Cho,et al.  Fluorescence sensing of microcracks based on cycloreversion of a dimeric anthracene moiety , 2012 .

[118]  AmendJohn,et al.  Soft Robotics Commercialization: Jamming Grippers from Research to Product. , 2016 .

[119]  B. Guo,et al.  Covalently Cross-Linked Elastomers with Self-Healing and Malleable Abilities Enabled by Boronic Ester Bonds. , 2018, ACS applied materials & interfaces.

[120]  Antoine Cully,et al.  Robots that can adapt like animals , 2014, Nature.

[121]  Jeffrey S. Moore,et al.  Polymer mechanochemistry: from destructive to productive. , 2015, Accounts of chemical research.

[122]  Fumiya Iida,et al.  Joint Entropy-Based Morphology Optimization of Soft Strain Sensor Networks for Functional Robustness , 2020, IEEE Sensors Journal.

[123]  Bram Vanderborght,et al.  Additive Manufacturing for Self-Healing Soft Robots. , 2020, Soft robotics.

[124]  Ming Qiu Zhang,et al.  Self-healing polymeric materials based on microencapsulated healing agents: From design to preparation , 2015 .

[125]  Jie Cao,et al.  Self-healing supramolecular hydrogels fabricated by cucurbit[8]uril-enhanced π-π interaction , 2016 .

[126]  Ming Qiu Zhang,et al.  Photo-stimulated self-healing polyurethane containing dihydroxyl coumarin derivatives , 2012 .

[127]  L. Imbernon,et al.  From landfilling to vitrimer chemistry in rubber life cycle , 2016 .

[128]  S. Zechel,et al.  How to Design a Self‐Healing Polymer: General Concepts of Dynamic Covalent Bonds and Their Application for Intrinsic Healable Materials , 2018 .

[129]  A. Haslett Electronics , 1948 .

[130]  Herman Terryn,et al.  Atomic force microscopy–based study of self-healing coatings based on reversible polymer network systems , 2014 .

[131]  M. Eremets,et al.  Ammonia as a case study for the spontaneous ionization of a simple hydrogen-bonded compound , 2014, Nature Communications.

[132]  Olivia R. Cromwell,et al.  Self-healing multiphase polymers via dynamic metal-ligand interactions. , 2014, Journal of the American Chemical Society.

[133]  Lingfeng Chen,et al.  Soft Robotics: Academic Insights and Perspectives Through Bibliometric Analysis , 2018, Soft robotics.

[134]  Andrew G. Glen,et al.  APPL , 2001 .

[135]  Antonius Broekhuis,et al.  Use of Diels–Alder Chemistry for Thermoreversible Cross-Linking of Rubbers: The Next Step toward Recycling of Rubber Products? , 2015 .

[136]  Zongliang Du,et al.  Light- and heat-triggered polyurethane based on dihydroxyl anthracene derivatives for self-healing applications , 2017 .

[137]  M. Demirel,et al.  Biosynthetic self-healing materials for soft machines , 2020, Nature Materials.

[138]  Nabarun Roy,et al.  DYNAMERS: dynamic polymers as self-healing materials. , 2015, Chemical Society reviews.

[139]  Ludwik Leibler,et al.  Catalytic Control of the Vitrimer Glass Transition. , 2012, ACS macro letters.

[140]  Tao Chen,et al.  Trends in polymeric shape memory hydrogels and hydrogel actuators , 2019, Polymer Chemistry.

[141]  G. Whitesides,et al.  Soft Machines That are Resistant to Puncture and That Self Seal , 2013, Advanced materials.

[142]  Jianfeng Fan,et al.  A robust and stretchable cross-linked rubber network with recyclable and self-healable capabilities based on dynamic covalent bonds , 2019, Journal of Materials Chemistry A.

[143]  Xinxing Zhang,et al.  Arbitrarily 3D Configurable Hygroscopic Robots with a Covalent–Noncovalent Interpenetrating Network and Self‐Healing Ability , 2019, Advanced materials.

[144]  Y. Dzenis,et al.  A highly stretchable, ultra-tough, remarkably tolerant, and robust self-healing glycerol-hydrogel for a dual-responsive soft actuator , 2019, Journal of Materials Chemistry A.

[145]  Henk M. Janssen,et al.  Self‐Healing Supramolecular Polymers In Action , 2012 .

[146]  Self-healing materials with embedded shape memory polymer fibers and wires , 2015 .

[147]  Zhong Lin Wang,et al.  3D printing of thermoreversible polyurethanes with targeted shape memory and precise in situ self-healing properties , 2019, Journal of Materials Chemistry A.

[148]  I. Bond,et al.  Biomimetic self-healing of advanced composite structures using hollow glass fibres , 2006 .

[149]  J. Lehn,et al.  Double dynamers: molecular and supramolecular double dynamic polymers. , 2005, Chemical communications.

[150]  D. Rus,et al.  Design, fabrication and control of soft robots , 2015, Nature.

[151]  S. Cai,et al.  Recyclable and self-repairable fluid-driven liquid crystal elastomer actuator. , 2020, ACS applied materials & interfaces.

[152]  Zuming Hu,et al.  Surface engineering of nanosilica for vitrimer composites , 2018 .

[153]  Matthew A. Robertson,et al.  New soft robots really suck: Vacuum-powered systems empower diverse capabilities , 2017, Science Robotics.

[154]  W. Ming,et al.  Self healing polymer coatings , 2007 .

[155]  Sam S. Yoon,et al.  Self-Healing Nanotextured Vascular Engineering Materials , 2019, Advanced Structured Materials.

[156]  Nancy R. Sottos,et al.  Microcapsules filled with reactive solutions for self-healing materials , 2009 .

[157]  Guoqiang Li,et al.  Advances in healing-on-demand polymers and polymer composites , 2016 .

[158]  Daniela Rus,et al.  Design, fabrication and control of origami robots , 2018, Nature Reviews Materials.

[159]  N. Ning,et al.  A self-healing dielectric supramolecular elastomer modified by TiO2/urea particles , 2019, Chemical Engineering Journal.

[160]  K. Landfester,et al.  Encapsulation of self-healing agents in polymer nanocapsules. , 2012, Small.

[161]  Jan-Anders E. Månson,et al.  Embedded Shape‐Memory Alloy Wires for Improved Performance of Self‐Healing Polymers , 2008 .

[162]  Ying Wang,et al.  UV-triggered self-healing polyurethane with enhanced stretchability and elasticity , 2019, Polymer.

[163]  Josh Bongard,et al.  A scalable pipeline for designing reconfigurable organisms , 2020, Proceedings of the National Academy of Sciences.

[164]  Stuart J. Rowan,et al.  A self-repairing, supramolecular polymer system: healability as a consequence of donor-acceptor pi-pi stacking interactions. , 2009, Chemical communications.

[165]  W. Kern,et al.  Self-healing of densely crosslinked thermoset polymers—a critical review , 2017 .

[166]  Ankit,et al.  Healable and flexible transparent heaters. , 2017, Nanoscale.

[167]  Bram Vanderborght,et al.  Self-Healing and High Interfacial Strength in Multi-Material Soft Pneumatic Robots via Reversible Diels–Alder Bonds , 2020 .

[168]  Daniel Fortin,et al.  Poly(vinyl alcohol)-Poly(ethylene glycol) Double-Network Hydrogel: A General Approach to Shape Memory and Self-Healing Functionalities. , 2015, Langmuir.

[169]  P. Ferraro,et al.  A skin-over-liquid platform with compliant microbumps actuated by pyro-EHD pressure , 2019, NPG Asia Materials.

[170]  LuNanshu,et al.  Flexible and Stretchable Electronics Paving the Way for Soft Robotics , 2014 .

[171]  Daniel A. Dalgo,et al.  A Clear, Strong, and Thermally Insulated Transparent Wood for Energy Efficient Windows , 2019, Advanced Functional Materials.

[172]  Andreas Pott,et al.  Mechatronic Control System for a Compliant and Precise Pneumatic Rotary Drive Unit , 2019, Actuators.

[173]  A. Agić,et al.  Thermal Degradation of Polyurethane Elastomers: Determination of Kinetic Parameters , 2003 .

[174]  Monika,et al.  Reactive and Functional Polymers , 2016 .

[175]  Cheng‐Hui Li,et al.  A dielectric elastomer actuator that can self-heal integrally. , 2020, ACS applied materials & interfaces.

[176]  Front , 2020, 2020 Fourth World Conference on Smart Trends in Systems, Security and Sustainability (WorldS4).

[177]  Bram Vanderborght,et al.  A Pneumatic Artificial Muscle Manufactured Out of Self-Healing Polymers That Can Repair Macroscopic Damages , 2018, IEEE Robotics and Automation Letters.

[178]  B. Guo,et al.  Mechanically Robust, Self-Healable, and Reprocessable Elastomers Enabled by Dynamic Dual Cross-Links , 2019, Macromolecules.

[179]  Kyu-Jin Cho,et al.  Soft Robotic Blocks: Introducing SoBL, a Fast-Build Modularized Design Block , 2016, IEEE Robotics & Automation Magazine.

[180]  Aishwarya V. Menon,et al.  The journey of self-healing and shape memory polyurethanes from bench to translational research , 2019, Polymer Chemistry.

[181]  Herman Terryn,et al.  Self-healing property characterization of reversible thermoset coatings , 2011 .

[182]  LuoMing,et al.  Toward Modular Soft Robotics: Proprioceptive Curvature Sensing and Sliding-Mode Control of Soft Bidirectional Bending Modules. , 2017 .

[183]  Cecilia Laschi,et al.  Soft robotics: a bioinspired evolution in robotics. , 2013, Trends in biotechnology.

[184]  Changyou Shao,et al.  High-Strength, Tough, and Self-Healing Nanocomposite Physical Hydrogels Based on the Synergistic Effects of Dynamic Hydrogen Bond and Dual Coordination Bonds. , 2017, ACS applied materials & interfaces.

[185]  Andrés S. Vázquez,et al.  Autonomous self-healing pneumatic McKibben muscle based on a new hydrogel material , 2020, 2020 3rd IEEE International Conference on Soft Robotics (RoboSoft).

[186]  Zhenan Bao,et al.  A Highly Stretchable and Autonomous Self-Healing Polymer Based on Combination of Pt···Pt and π-π Interactions. , 2016, Macromolecular rapid communications.

[187]  Kei Saito,et al.  Photo-reversible dimerisation reactions and their applications in polymeric systems , 2014 .

[188]  N. Sottos,et al.  Restoration of Large Damage Volumes in Polymers , 2014, Science.

[189]  Ujjaval Gupta,et al.  Soft robots based on dielectric elastomer actuators: a review , 2019, Smart Materials and Structures.

[190]  Russell J. Varley,et al.  Ionomers as Self Healing Polymers , 2007 .

[191]  Adrian Bejan,et al.  Networks of channels for self-healing composite materials , 2006 .

[192]  Nele De Belie,et al.  Self-Healing in Cementitious Materials—A Review , 2013 .

[193]  Jean-Baptiste Mouret,et al.  Adaptive and Resilient Soft Tensegrity Robots , 2017, Soft robotics.

[194]  Nancy R. Sottos,et al.  Polydimethylsiloxane‐Based Self‐Healing Materials , 2006 .

[195]  Hartmut Fischer,et al.  Degradation mechanism of silicone glues under UV irradiation and options for designing materials with increased stability , 2013 .

[196]  J. Brancart,et al.  A novel approach for the closure of large damage in self-healing elastomers using magnetic particles , 2020 .

[197]  G. Assche,et al.  Creation of a nanovascular network by electrospun sacrificial nanofibers for self-healing applications and its effect on the flexural properties of the bulk material , 2016 .

[198]  M. Rong,et al.  Polymer engineering based on reversible covalent chemistry: A promising innovative pathway towards new materials and new functionalities , 2018 .

[199]  Z. Man,et al.  The Potential of Microencapsulated Self-healing Materials for Microcracks Recovery in Self-healing Composite Systems: A Review , 2016 .

[200]  R. Sijbesma,et al.  Mechanocatalysis: forcing latent catalysts into action , 2013 .

[201]  George P Mylonas,et al.  Soft Robotics in Minimally Invasive Surgery , 2019, Soft robotics.

[202]  C. D. Onal,et al.  A modular approach to soft robots , 2012, 2012 4th IEEE RAS & EMBS International Conference on Biomedical Robotics and Biomechatronics (BioRob).

[203]  Bram Vanderborght,et al.  Toward Self-Healing Actuators: A Preliminary Concept , 2016, IEEE Transactions on Robotics.

[204]  H. Otsuka,et al.  Self‐healing Polymers through Dynamic Covalent Chemistry , 2017 .

[205]  de Jeff Hosson,et al.  Self Healing Materials. An Alternative Approach to 20 Centuries of Materials Science , 2007 .

[206]  J. Brancart,et al.  The influence of stereochemistry on the reactivity of the Diels–Alder cycloaddition and the implications for reversible network polymerization , 2019, Polymer Chemistry.

[207]  Xing Zhou,et al.  Flexible Self-Repairing Materials for Wearable Sensing Applications: Elastomers and Hydrogels. , 2020, Macromolecular rapid communications.

[208]  Feifei Chen,et al.  Stimuli-responsive functional materials for soft robotics. , 2020, Journal of materials chemistry. B.

[209]  Russell J. Varley,et al.  Towards an understanding of thermally activated self-healing of an ionomer system during ballistic penetration , 2008 .

[210]  Zhanhu Guo,et al.  Multistimuli-Responsive Intrinsic Self-Healing Epoxy Resin Constructed by Host–Guest Interactions , 2018, Macromolecules.

[211]  Gregory S. Chirikjian,et al.  Modular Self-Reconfigurable Robot Systems [Grand Challenges of Robotics] , 2007, IEEE Robotics & Automation Magazine.

[212]  Robert J. Wood,et al.  A Resilient, Untethered Soft Robot , 2014 .

[213]  R. Wool Self-healing materials: a review. , 2008, Soft matter.

[214]  Yanhua Zhao,et al.  Effect of failure modes on healing behavior and multiple healing capability of self-healing polyurethanes , 2018, Construction and Building Materials.

[215]  Jong Won Chung,et al.  Stretchable Self-Healing Polymeric Dielectrics Cross-Linked Through Metal-Ligand Coordination. , 2016, Journal of the American Chemical Society.

[216]  Bram Vanderborght,et al.  Room Temperature Self-Healing in Soft Pneumatic Robotics: Autonomous Self-Healing in a Diels-Alder Polymer Network , 2020, IEEE Robotics & Automation Magazine.

[217]  Thomas J. Wallin,et al.  3D printing of soft robotic systems , 2018, Nature Reviews Materials.

[218]  Yi Sun,et al.  A Flexible Fabrication Approach Toward the Shape Engineering of Microscale Soft Pneumatic Actuators , 2017, IEEE Robotics and Automation Letters.

[219]  Carmel Majidi,et al.  Soft Electronic Skin for Multi‐Site Damage Detection and Localization , 2019, Advanced Functional Materials.

[220]  Sanghyun Yoon,et al.  Soft Robotics: A Review of Recent Developments of Pneumatic Soft Actuators , 2020, Actuators.

[221]  Lijuan Zhao,et al.  Super tough and strong self-healing elastomers based on polyampholytes , 2018 .

[222]  Mehdi B. Zanjani,et al.  Dual-dynamic interpenetrated networks tuned through macromolecular architecture , 2019, Polymer Chemistry.

[223]  N. Ning,et al.  Photothermal-Induced Self-Healable and Reconfigurable Shape Memory Bio-Based Elastomer with Recyclable Ability. , 2018, ACS applied materials & interfaces.

[224]  H. Fischer,et al.  Diels-Alder based, thermo-reversible cross-linked epoxies for use in self-healing composites , 2015 .

[225]  Antonio López-Díaz,et al.  Autonomous self-healing hydrogel with anti-drying properties and applications in soft robotics , 2020 .

[226]  Yanju Liu,et al.  Shape-memory polymers and their composites: Stimulus methods and applications , 2011 .

[227]  S. Ghosh,et al.  Self‐Healing Materials: Fundamentals, Design Strategies, and Applications , 2009 .

[228]  Min-Woo Han,et al.  An Overview of Shape Memory Alloy-Coupled Actuators and Robots. , 2017, Soft robotics.

[229]  Danhquang Tran,et al.  Dielectric elastomer actuators based on stretchable and self-healable hydrogel electrodes , 2019, Royal Society Open Science.

[230]  L. Leibler,et al.  Self-Healing of Unentangled Polymer Networks with Reversible Bonds. , 2013, Macromolecules.

[231]  C. Dry Passive Smart Materials for Sensing and Actuation , 1993 .

[232]  Dahee Jung,et al.  Cross-linking dots on metal oxides , 2019, NPG Asia Materials.

[233]  H. Grande,et al.  The processability of a poly(urea-urethane) elastomer reversibly crosslinked with aromatic disulfide bridges , 2014 .

[234]  Zhuangjian Liu,et al.  Self-Healing Four-Dimensional Printing with an Ultraviolet Curable Double-Network Shape Memory Polymer System. , 2019, ACS applied materials & interfaces.

[235]  Bert Klumperman,et al.  Self-Healing Materials Based on Disulfide Links , 2011 .

[236]  Saul Utrera-Barrios,et al.  Evolution of self-healing elastomers, from extrinsic to combined intrinsic mechanisms: a review , 2020, Materials Horizons.

[237]  Zhenyuan Zhang,et al.  Pneumatically Actuated Self-Healing Bionic Crawling Soft Robot , 2020, J. Intell. Robotic Syst..

[238]  Zong-liang Du,et al.  Mechanically robust self-healing and recyclable flame-retarded polyurethane elastomer based on thermoreversible crosslinking network and multiple hydrogen bonds , 2020 .

[239]  Reza Rizvi,et al.  High‐Throughput Continuous Production of Shear‐Exfoliated 2D Layered Materials using Compressible Flows , 2018, Advanced materials.

[240]  Michael U. Ocheje,et al.  Stretchable electronics: recent progress in the preparation of stretchable and self-healing semiconducting conjugated polymers , 2017 .

[241]  Ying-Chih Lai,et al.  Vitrimer Elastomer‐Based Jigsaw Puzzle‐Like Healable Triboelectric Nanogenerator for Self‐Powered Wearable Electronics , 2018, Advanced materials.

[242]  Carmel Majidi,et al.  A multifunctional shape-morphing elastomer with liquid metal inclusions , 2019, Proceedings of the National Academy of Sciences.

[243]  Stuart J Rowan,et al.  Dynamic covalent chemistry. , 2002, Angewandte Chemie.

[244]  Xueting Shi,et al.  Self-healing behavior of polyurethanes based on dual actions of thermo-reversible Diels-Alder reaction and thermal movement of molecular chains , 2017 .

[245]  Aaron M Kushner,et al.  Multiphase design of autonomic self-healing thermoplastic elastomers. , 2012, Nature chemistry.

[246]  S. V. D. Zwaag Self healing materials : an alternative approach to 20 centuries of materials science , 2007 .

[247]  Ludwik Leibler,et al.  Silica-Like Malleable Materials from Permanent Organic Networks , 2011, Science.

[248]  Michael Nosonovsky,et al.  Physical chemistry of self-organization and self-healing in metals. , 2009, Physical chemistry chemical physics : PCCP.

[249]  G. P. Simon,et al.  Photoreversible Smart Polymers Based on 2π + 2π Cycloaddition Reactions: Nanofilms to Self-Healing Films , 2019, Macromolecules.