Chemical Characterization of Aerosol Particles Using On-Chip Photonic Cavity Enhanced Spectroscopy.

We demonstrate the chemical characterization of aerosol particles with on-chip spectroscopy using a photonic cavity enhanced silicon nitride (Si3N4) racetrack resonator-based sensor. The sensor operates over a broad and continuous wavelength range, showing cavity enhanced sensitivity at specific resonant wavelengths. Analysis of the relative change in the quality factor of the cavity resonances successfully yields the absorption spectrum of the aerosol particles deposited on the resonators. Detection of N-methyl aniline-based aerosol in the near infrared (NIR) range of 1500 to 1600 nm is demonstrated. Our aerosol sensor spectral data compares favorably with that from a commercial spectrometer, indicating good accuracy. The small size of the device is advantageous in remote, environmental, medical, and body-wearable sensing applications.

[1]  Panich Intra Aerosol size measurement system using electrical mobility technique = ระบบการวัดขนาดละอองลอยในอากาศโดยใช้เทคนิคการเคลื่อนตัวทางไฟฟ้า / Panich Intra , 2006 .

[2]  R. Linker,et al.  Detection and quantification of water-based aerosols using active open-path FTIR , 2016, Scientific reports.

[3]  M. Kerker Light Scattering Instrumentation for Aerosol Studies: An Historical Overview , 1997 .

[4]  Ryan C Bailey,et al.  Applications of Optical Microcavity Resonators in Analytical Chemistry. , 2016, Annual review of analytical chemistry.

[5]  Junji Cao The Importance of Aerosols in the Earth System: Science and Engineering Perspectives , 2017, Aerosol Science and Engineering.

[6]  J. Philip,et al.  Young's modulus of silicon nitride used in scanning force microscope cantilevers , 2004 .

[7]  Kathleen Richardson,et al.  Demonstration of chalcogenide glass racetrack microresonators. , 2008, Optics letters.

[8]  S. Ozdemir,et al.  Raman-gain induced loss-compensation in whispering-gallery-microresonators and single-nanoparticle detection with whispering-gallery Raman-microlasers , 2014, 1401.2033.

[9]  H. Tang,et al.  Nano-Optomechanical Resonators in Microfluidics. , 2015, Nano letters.

[10]  T. J. Kippenberg,et al.  Ultra-high-Q toroid microcavity on a chip , 2003, Nature.

[11]  F. Pope,et al.  of Birmingham Evaluation of a low-cost optical particle counter (Alphasense OPC-N2) for ambient air monitoring , 2018 .

[12]  Judith Su,et al.  Label-Free Biological and Chemical Sensing Using Whispering Gallery Mode Optical Resonators: Past, Present, and Future , 2017, Sensors.

[13]  Franco Cosi,et al.  Optical Microspherical Resonators for Biomedical Sensing , 2011, Sensors.

[14]  R. Tiwari,et al.  Drug delivery systems: An updated review , 2012, International journal of pharmaceutical investigation.

[15]  Lan Yang,et al.  On-chip Single Nanoparticle Detection and Sizing by Mode Splitting in an Ultra-high-Q Microresonator , 2009 .

[16]  G. Bae,et al.  Real-Time Fluorescence Measurement of Airborne Bacterial Particles Using an Aerosol Fluorescence Sensor with Dual Ultraviolet- and Visible-Fluorescence Channels , 2012 .

[17]  Peng Jiang,et al.  A Miniature Aerosol Sensor for Detecting Polydisperse Airborne Ultrafine Particles , 2017, Sensors.

[18]  Yong Xu,et al.  Highly sensitive nano-aerosol detection based on the whispering-gallery-mode in cylindrical optical fiber resonators , 2016 .

[19]  Roshan L. Aggarwal,et al.  Chemical aerosol detection and identification using Raman scattering , 2014 .

[20]  B. Rubin Air and soul: the science and application of aerosol therapy. , 2010, Respiratory care.

[21]  Pao Tai Lin,et al.  Mid-infrared spectrometer using opto-nanofluidic slot-waveguide for label-free on-chip chemical sensing. , 2014, Nano letters.

[22]  R. Verma,et al.  Inhalation drug delivery devices: technology update , 2015, Medical devices.

[23]  V. R. Dantham,et al.  Taking whispering gallery-mode single virus detection and sizing to the limit , 2012 .

[24]  Satoshi Kondo,et al.  Field-deployable rapid multiple biosensing system for detection of chemical and biological warfare agents , 2018, Microsystems & Nanoengineering.

[25]  M. Lipson,et al.  Cavity-enhanced on-chip absorption spectroscopy using microring resonators. , 2008, Optics express.

[26]  L. Chrostowski,et al.  Silicon Photonics Design: From Devices to Systems , 2015 .

[27]  H. Cai,et al.  Hybrid Photonic Cavity with Metal-Organic Framework Coatings for the Ultra-Sensitive Detection of Volatile Organic Compounds with High Immunity to Humidity , 2017, Scientific Reports.

[28]  Alena Bartonova,et al.  Can commercial low-cost sensor platforms contribute to air quality monitoring and exposure estimates? , 2017, Environment international.