Making chemicals with electricity

Hydrogen can be produced in electrically heated reactors, reducing CO2 emissions Vast amounts of energy are needed to synthesize the hundreds of millions of tons of chemicals used in everyday life each year. To meet that demand, the chemical industry uses the energy released during fuel combustion, thereby producing a seventh of the anthropogenic emissions of greenhouse gases. Climate change makes it mandatory to replace fossil fuels in chemical production processes and reduce their climate impact (1–3). On page 756 of this issue, Wismann et al. (4) focus on reducing the CO2 emissions created during the production of molecular hydrogen (H2), a key building block for ammonia-derived fertilizers, through steam reforming of methane. This industrial process releases 9 kg of CO2 per kg of H2, a quarter of which comes from fuel combustion.

[1]  Alexandre F. P. Ferreira,et al.  Electrical conductive 3D-printed monolith adsorbent for CO2 capture , 2019, Microporous and Mesoporous Materials.

[2]  Zachary J. Schiffer,et al.  Electrification and Decarbonization of the Chemical Industry , 2017 .

[3]  W. Leitner,et al.  Advanced Biofuels and Beyond: Chemistry Solutions for Propulsion and Production. , 2017, Angewandte Chemie.

[4]  Matthew R. Shaner,et al.  Net-zero emissions energy systems , 2018, Science.

[5]  T. Wassermann,et al.  Socio-technical-economic assessment of power-to-X: Potentials and limitations for an integration into the German energy system , 2019, Energy Research & Social Science.

[6]  André Faaij,et al.  A review at the role of storage in energy systems with a focus on Power to Gas and long-term storage , 2018 .

[7]  Ib Chorkendorff,et al.  Electrified methane reforming: A compact approach to greener industrial hydrogen production , 2019, Science.

[8]  S. Sorrell,et al.  Sociotechnical transitions for deep decarbonization , 2017, Science.

[9]  G. Stefanidis,et al.  Direct methane-to-ethylene conversion in a nanosecond pulsed discharge , 2018, Fuel.

[10]  J. L. Hueso,et al.  Escaping undesired gas-phase chemistry: Microwave-driven selectivity enhancement in heterogeneous catalytic reactors , 2019, Science Advances.

[11]  V. Galvita,et al.  Upgrading the value of anaerobic digestion via chemical production from grid injected biomethane , 2018 .

[12]  Alexander M. Bradshaw,et al.  Decarbonisation of transport: options and challenges , 2019 .